@prefix adms: . @prefix cnt: . @prefix dcat: . @prefix dcatap: . @prefix dct: . @prefix eli: . @prefix foaf: . @prefix gsp: . @prefix locn: . @prefix skos: . @prefix vcard: . @prefix xsd: . a dcat:Dataset ; dcatap:applicableLegislation ; dcatap:hvdCategory ; dct:accessRights ; dct:conformsTo ; dct:creator [ a foaf:Agent ; dct:identifier "E05068001" ; dct:type ; foaf:mbox ; foaf:name "Oller-Ruiz, A., Campillo, N., Hernandez-Cordoba, M., Gilabert, J. y Vinas, P."@en ] ; dct:description "The use of dispersive liquid-liquid microextraction (DLLME) is proposed for the preconcentration of thirteen lipophilic marine toxins in seawater samples. For this purpose, 0.5 mL of methanol and 440 mu L of chloroform were injected into 12 mL of sample. The enriched organic phase, once evaporated and reconstituted in methanol, was analyzed by reversed-phase liquid chromatography with triple-quadrupole tandem mass spectrometry. A central composite design multivariate method was used to optimize the interrelated parameters affecting DLLME efficiency. The absence of any matrix effect in the samples allowed them to be quantified against aqueous standards. The optimized procedure was validated by recovery studies, which provided values in the 82-123% range. The detection limits varied between 0.2 and 5.7 ng L-1, depending on the analyte, and the intraday precision values were in the 0.1-7.5% range in terms of relative standard deviation. Ten water samples taken from different points of the Mar Menor lagoon were analyzed and were found to be free of the studied toxins."@en, "The use of dispersive liquid-liquid microextraction (DLLME) is proposed for the preconcentration of thirteen lipophilic marine toxins in seawater samples. For this purpose, 0.5 mL of methanol and 440 mu L of chloroform were injected into 12 mL of sample. The enriched organic phase, once evaporated and reconstituted in methanol, was analyzed by reversed-phase liquid chromatography with triple-quadrupole tandem mass spectrometry. A central composite design multivariate method was used to optimize the interrelated parameters affecting DLLME efficiency. The absence of any matrix effect in the samples allowed them to be quantified against aqueous standards. The optimized procedure was validated by recovery studies, which provided values in the 82-123% range. The detection limits varied between 0.2 and 5.7 ng L-1, depending on the analyte, and the intraday precision values were in the 0.1-7.5% range in terms of relative standard deviation. Ten water samples taken from different points of the Mar Menor lagoon were analyzed and were found to be free of the studied toxins."@es ; dct:identifier "dd7326be-c55f-577e-b5ca-f55df15d299b" ; dct:issued "2024-11-05T00:00:00+00:00"^^xsd:dateTime ; dct:language ; dct:license ; dct:modified "2026-06-25T00:00:00+00:00"^^xsd:dateTime ; dct:publisher ; dct:spatial ; dct:title "Monitoring Lipophilic Toxins in Seawater Using Dispersive Liquid-Liquid Microextraction and Liquid Chromatography with Triple Quadrupole Mass Spectrometry"@en, "Monitoring Lipophilic Toxins in Seawater Using Dispersive Liquid-Liquid Microextraction and Liquid Chromatography with Triple Quadrupole Mass Spectrometry"@es ; dct:type ; adms:identifier "DOI: 10.3390/toxins13010057" ; adms:status ; dcat:contactPoint ; dcat:distribution ; dcat:keyword "contaminacion"@en ; dcat:landingPage ; dcat:theme , . a dct:Location ; skos:prefLabel "España" ; dcat:bbox "POLYGON ((-18.1600 27.6400, 4.3200 27.6400, 4.3200 43.7900, -18.1600 43.7900, -18.1600 27.6400))"^^gsp:wktLiteral ; dcat:centroid "POINT (-6.9200 35.7150)"^^gsp:wktLiteral ; locn:geometry "POLYGON ((-18.1600 27.6400, 4.3200 27.6400, 4.3200 43.7900, -18.1600 43.7900, -18.1600 27.6400))"^^gsp:wktLiteral . a dct:LinguisticSystem . a dct:LinguisticSystem . a foaf:Agent ; dct:type ; vcard:hasEmail ; foaf:homepage ; foaf:name "Área de Banco de Datos de la Naturaleza. Dirección General Biodiversidad, Bosques y Desertificación. Ministerio para la Transición Ecológica y el Reto Demográfico"@en . a foaf:Document . a dcat:Distribution ; dcatap:applicableLegislation ; dcatap:availability ; dct:accessRights ; dct:format ; dct:issued "2021-01-13T00:00:00+00:00"^^xsd:dateTime ; dct:language ; dct:license ; dct:modified "2026-06-25T00:00:00+00:00"^^xsd:dateTime ; dct:title "Distribución HTML"@en, "Distribución HTML"@es ; cnt:characterEncoding "UTF-8" ; dcat:accessURL ; dcat:mediaType . a vcard:Kind ; vcard:fn "Organismo publicador del Catálogo"@en ; vcard:hasEmail ; vcard:hasURL ; vcard:role . a dct:Standard . a eli:LegalResource . dct:type .