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en Mobilisation of AS and trace metals in saline, acidic Sopolic Technosols: the role of the rhizosphere and flooding conditions -
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) en Mobilisation of AS and trace metals in saline, acidic Sopolic Technosols: the role of the rhizosphere and flooding conditions
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| 93 | "notes": "Purpose The aim of this work was to study the risk of As | 103 | "notes": "Purpose The aim of this work was to study the risk of As | ||
| 94 | and metal pollution in saline wetlands affected by slightly acidic | 104 | and metal pollution in saline wetlands affected by slightly acidic | ||
| 95 | mine wastes, in the presence or absence of a plant rhizosphere, under | 105 | mine wastes, in the presence or absence of a plant rhizosphere, under | ||
| 96 | different flooding regimes. Some guide lines for management will be | 106 | different flooding regimes. Some guide lines for management will be | ||
| 97 | proposed in order to minimise the risk of metal leaching in | 107 | proposed in order to minimise the risk of metal leaching in | ||
| 98 | metal-polluted salt marshes. Materials and methods A microcosm | 108 | metal-polluted salt marshes. Materials and methods A microcosm | ||
| 99 | experiment was conducted to assess the influence of two flooding | 109 | experiment was conducted to assess the influence of two flooding | ||
| 100 | regimes (continuous or alternating) and the presence of rhizosphere | 110 | regimes (continuous or alternating) and the presence of rhizosphere | ||
| 101 | (Sarcocornia fruticosa and Phragmites australis) on the mobilisation | 111 | (Sarcocornia fruticosa and Phragmites australis) on the mobilisation | ||
| 102 | of As, Cd, Mn, Pb, Zn and Fe in a slightly acidic, saline Spolic | 112 | of As, Cd, Mn, Pb, Zn and Fe in a slightly acidic, saline Spolic | ||
| 103 | Technosol (pH\u22486.5; total concentrations:551 mg kg\u22121 As, | 113 | Technosol (pH\u22486.5; total concentrations:551 mg kg\u22121 As, | ||
| 104 | 5,640 mg kg\u22121 Pb, 5,299 mg kg\u22121 Zn). Results and discussion | 114 | 5,640 mg kg\u22121 Pb, 5,299 mg kg\u22121 Zn). Results and discussion | ||
| 105 | Metal and As pore water concen trations decreased with flooding time | 115 | Metal and As pore water concen trations decreased with flooding time | ||
| 106 | (e.g. from approxi mately 1,700 \u03bcg L\u22121 Cd, 190 mg L\u22121 | 116 | (e.g. from approxi mately 1,700 \u03bcg L\u22121 Cd, 190 mg L\u22121 | ||
| 107 | Zn and 230 mg L\u22121 Mn to <400 \u03bcg L\u22121 Cd, <35 mg L\u22121 | 117 | Zn and 230 mg L\u22121 Mn to <400 \u03bcg L\u22121 Cd, <35 mg L\u22121 | ||
| 108 | Zn, and 50 mg L\u22121 Mn). A sequential extraction showed that Fe and | 118 | Zn, and 50 mg L\u22121 Mn). A sequential extraction showed that Fe and | ||
| 109 | As were associated mainly with the silicate fraction of the soil, but | 119 | As were associated mainly with the silicate fraction of the soil, but | ||
| 110 | most of the Mn, Cd, Pb and Zn belonged to the reactive fraction. The | 120 | most of the Mn, Cd, Pb and Zn belonged to the reactive fraction. The | ||
| 111 | rhizosphere of Sarcocornia induced a lower pH, which facilitated | 121 | rhizosphere of Sarcocornia induced a lower pH, which facilitated | ||
| 112 | higher concentrations of soluble Fe. However, in pots without plants | 122 | higher concentrations of soluble Fe. However, in pots without plants | ||
| 113 | and pots with Phragmites, the combination of Eh and pH led to | 123 | and pots with Phragmites, the combination of Eh and pH led to | ||
| 114 | conditions for formation of siderite, and hence the concentrations of | 124 | conditions for formation of siderite, and hence the concentrations of | ||
| 115 | soluble Fe were lower. The concentrations of Mn, Cd, Pb and Zn were | 125 | soluble Fe were lower. The concentrations of Mn, Cd, Pb and Zn were | ||
| 116 | lower in vegetated pots, probably due to precipitation of metal | 126 | lower in vegetated pots, probably due to precipitation of metal | ||
| 117 | carbonates favoured by gas exchange in the rhizosphere. Conclusions | 127 | carbonates favoured by gas exchange in the rhizosphere. Conclusions | ||
| 118 | The rhizosphere modified soil conditions during the period of flooding | 128 | The rhizosphere modified soil conditions during the period of flooding | ||
| 119 | and this affected the dynamics of metals. The high levels of soluble | 129 | and this affected the dynamics of metals. The high levels of soluble | ||
| 120 | metals pose a risk for leaching, transfer to the food web and toxicity | 130 | metals pose a risk for leaching, transfer to the food web and toxicity | ||
| 121 | for living organisms. In order to reduce the risks, we propose the | 131 | for living organisms. In order to reduce the risks, we propose the | ||
| 122 | water saturation of the soil and the establishments of a plant | 132 | water saturation of the soil and the establishments of a plant | ||
| 123 | cover.", | 133 | cover.", | ||
| 124 | "notes_translated": { | 134 | "notes_translated": { | ||
| 125 | "es": "Purpose The aim of this work was to study the risk of As | 135 | "es": "Purpose The aim of this work was to study the risk of As | ||
| 126 | and metal pollution in saline wetlands affected by slightly acidic | 136 | and metal pollution in saline wetlands affected by slightly acidic | ||
| 127 | mine wastes, in the presence or absence of a plant rhizosphere, under | 137 | mine wastes, in the presence or absence of a plant rhizosphere, under | ||
| 128 | different flooding regimes. Some guide lines for management will be | 138 | different flooding regimes. Some guide lines for management will be | ||
| 129 | proposed in order to minimise the risk of metal leaching in | 139 | proposed in order to minimise the risk of metal leaching in | ||
| 130 | metal-polluted salt marshes. Materials and methods A microcosm | 140 | metal-polluted salt marshes. Materials and methods A microcosm | ||
| 131 | experiment was conducted to assess the influence of two flooding | 141 | experiment was conducted to assess the influence of two flooding | ||
| 132 | regimes (continuous or alternating) and the presence of rhizosphere | 142 | regimes (continuous or alternating) and the presence of rhizosphere | ||
| 133 | (Sarcocornia fruticosa and Phragmites australis) on the mobilisation | 143 | (Sarcocornia fruticosa and Phragmites australis) on the mobilisation | ||
| 134 | of As, Cd, Mn, Pb, Zn and Fe in a slightly acidic, saline Spolic | 144 | of As, Cd, Mn, Pb, Zn and Fe in a slightly acidic, saline Spolic | ||
| 135 | Technosol (pH\u22486.5; total concentrations:551 mg kg\u22121 As, | 145 | Technosol (pH\u22486.5; total concentrations:551 mg kg\u22121 As, | ||
| 136 | 5,640 mg kg\u22121 Pb, 5,299 mg kg\u22121 Zn). Results and discussion | 146 | 5,640 mg kg\u22121 Pb, 5,299 mg kg\u22121 Zn). Results and discussion | ||
| 137 | Metal and As pore water concen trations decreased with flooding time | 147 | Metal and As pore water concen trations decreased with flooding time | ||
| 138 | (e.g. from approxi mately 1,700 \u03bcg L\u22121 Cd, 190 mg L\u22121 | 148 | (e.g. from approxi mately 1,700 \u03bcg L\u22121 Cd, 190 mg L\u22121 | ||
| 139 | Zn and 230 mg L\u22121 Mn to <400 \u03bcg L\u22121 Cd, <35 mg L\u22121 | 149 | Zn and 230 mg L\u22121 Mn to <400 \u03bcg L\u22121 Cd, <35 mg L\u22121 | ||
| 140 | Zn, and 50 mg L\u22121 Mn). A sequential extraction showed that Fe and | 150 | Zn, and 50 mg L\u22121 Mn). A sequential extraction showed that Fe and | ||
| 141 | As were associated mainly with the silicate fraction of the soil, but | 151 | As were associated mainly with the silicate fraction of the soil, but | ||
| 142 | most of the Mn, Cd, Pb and Zn belonged to the reactive fraction. The | 152 | most of the Mn, Cd, Pb and Zn belonged to the reactive fraction. The | ||
| 143 | rhizosphere of Sarcocornia induced a lower pH, which facilitated | 153 | rhizosphere of Sarcocornia induced a lower pH, which facilitated | ||
| 144 | higher concentrations of soluble Fe. However, in pots without plants | 154 | higher concentrations of soluble Fe. However, in pots without plants | ||
| 145 | and pots with Phragmites, the combination of Eh and pH led to | 155 | and pots with Phragmites, the combination of Eh and pH led to | ||
| 146 | conditions for formation of siderite, and hence the concentrations of | 156 | conditions for formation of siderite, and hence the concentrations of | ||
| 147 | soluble Fe were lower. The concentrations of Mn, Cd, Pb and Zn were | 157 | soluble Fe were lower. The concentrations of Mn, Cd, Pb and Zn were | ||
| 148 | lower in vegetated pots, probably due to precipitation of metal | 158 | lower in vegetated pots, probably due to precipitation of metal | ||
| 149 | carbonates favoured by gas exchange in the rhizosphere. Conclusions | 159 | carbonates favoured by gas exchange in the rhizosphere. Conclusions | ||
| 150 | The rhizosphere modified soil conditions during the period of flooding | 160 | The rhizosphere modified soil conditions during the period of flooding | ||
| 151 | and this affected the dynamics of metals. The high levels of soluble | 161 | and this affected the dynamics of metals. The high levels of soluble | ||
| 152 | metals pose a risk for leaching, transfer to the food web and toxicity | 162 | metals pose a risk for leaching, transfer to the food web and toxicity | ||
| 153 | for living organisms. In order to reduce the risks, we propose the | 163 | for living organisms. In order to reduce the risks, we propose the | ||
| 154 | water saturation of the soil and the establishments of a plant cover." | 164 | water saturation of the soil and the establishments of a plant cover." | ||
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| 309 | "title": "Mobilisation of AS and trace metals in saline, acidic | 319 | "title": "Mobilisation of AS and trace metals in saline, acidic | ||
| 310 | Sopolic Technosols: the role of the rhizosphere and flooding | 320 | Sopolic Technosols: the role of the rhizosphere and flooding | ||
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| 313 | "es": "Mobilisation of AS and trace metals in saline, acidic | 323 | "es": "Mobilisation of AS and trace metals in saline, acidic | ||
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| 315 | conditions" | 325 | conditions" | ||
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| 319 | "type": "dataset", | 329 | "type": "dataset", | ||
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